Page 12 - Guide to Managing Trade Effluent - 2023
P. 12

Treatment Solutions                                                                                                                                         Main Pollutant



        Effluent Treatment is commonly categorised according to the following stages:                                              Pollutant                      Treatment                                 Comments

        Preliminary Treatment:  Initial recovery of large solids by screening. Various types of static and                                           Acidic pH adjusted through the addition of an   Accurate pH adjustment from either highly
                                                                                                                                                     alkali e.g. Sodium Hydroxide or Lime.
                                                                                                                                                                                               alkaline or highly acidic conditions may
        mechanical screens may be used. Preliminary treatment can also include the operation of                                                                                                be difficult to achieve using in-line dosing
        “balancing tanks” used to even out the flow and strength of the effluent prior to subsequent                                   pH            Alkali pH adjusted through the addition of an   techniques
        treatment.                                                                                                                                   acid e.g. Hydrochloric sulphuric or carbon   Use of buffer/mix tanks to allow more accurate
                                                                                                                                                     dioxide
                                                                                                                                                                                               control of the treated water pH may be
        Primary Treatment:  This stage is characterised by the removal of gross levels of suspended                                                                                            beneficial.
        particles and/or the oil and grease. Commonly involve the use of pH adjustment unit, oil water                                               Treatment within settlement tanks, upward   The solids are usually recovered as a sludge.
        separators, settlement units (clarifiers), or dissolved floatation units (DAF).                                                              flow clarifiers and lamella clarifiers to recover   Further dewatering and/or thickening of
                                                                                                                                                     medium and coarse particles which will settle   the sludge may be required as a means of
                                                                                                                                                     to the base of the unit                   reducing waste disposal costs and improving the
        Secondary Treatment:  Frequently biological treatment using microbes to remove organic                                                                                                 handleability of the materials.
        materials which have not been removed by the previous treatment stages. Treatment is either                                                  Low density (buoyant) solids e.g. organic
        down the effluent. The use of anaerobic reactors is usually a first stage treatment to break down                                            waste and algae may be recovered using    Filtration systems will periodically need to be
                                                                                                                                                     dissolved air flotation techniques.
                                                                                                                                                                                               backwashed and/or the filter media replenished.
        particularly high strength effluent before treatments in a second aerobic stage. Both processes                            Suspended                                                   Filtration is commonly seen as a polishing stage
        are relatively slow and may necessitate the use of large tanks/lagoons or compact mechanical                                  Solids         Addition of coagulants and flocculants    used to recover residual low concentration of
        systems. Biological treatment is a sensitive process requiring controlled operating conditions with                                          to recover fine (clay sized) and colloidal   solids.
                                                                                                                                                     particles.
        constant effluent supply.                                                                                                                                                              Where high concentration of suspended
                                                                                                                                                     Low concentrations of suspended solids may   particles are present, a two stage approach
        Tertiary Treatment:  Considered to be a final cleaning/polishing stage, used if necessary to remove                                          be recovered by water filtration          settlement or floatation to remove gross
        any remaining traces of contamination or to produce a high quality treated effluent that may                                                                                           concentrations of solids, followed by filtration to
                                                                                                                                                                                               polish the effluent may be implemented.
        enable the water to be re-used (recycled) for specific low risk uses. Treatment process can include
        fine filtration (sand filtration, nano-filtration), reverse osmosis, nitrification, granular activated                                       May be present as either suspended particles   High BOD levels may inhibit biological
                                                                                                                                                     (see suspended solids) or dissolved.
                                                                                                                                                                                               activity, requiring need for pre-treatment or
        carbon or sterilisation/disinfection.                                                                                                                                                  homogenisation of differing waste streams to
                                                                                                                                       BOD           Where present as dissolved BOD, commonly   achieve a satisfactory level.
                                                                                                                                                     is treated via biological (destruction using
                                                                                                                                                     microbes) or chemical oxidation.          Biological systems need to be operated on a
                                                                                                                                                                                               continuous basis to prevent microbes becoming
                                                                                                                                                                                               dormant.
                                                                                                                                                     JFH May be present as either suspended    Stats Chemical oxidation systems can be
                                                                                                                                                     particles (see suspended solids) or dissolved.  operated in either a batch or continuous basis.
                                                                                                                                      COD            May be resistant to biological destruction,
                                                                                                                                                     necessitating the need for addition of a
                                                                                                                                                     chemical to oxidise the materials, eg addition
                                                                                                                                                     of hydrogen peroxide.

                                                                                                                                                     JFH Typically removed by precipitation as an   The precipitated metals will be recovered as a
                                                                                                                                                     insoluble compound eg Hydroxide.          sludge, depending on the metal recovered this
                                                                                                                                                                                               sludge may either be classified as non-hazardous
                                                                                                                                                     To minimise the concentration of metals in the   or as hazardous.
                                                                                                                                                     treated water, pH adjust may be required to
                                                                                                                                                     adjust the pH of the water to the low point on   Dewatering of the sludge is normally undertaken
                                                                                                                                      Metals         the metals, solubility curve.             as a a means of minimising the moisture content,
                                                                                                                                                                                               thereby reducing disposal costs.
                                                                                                                                                     Where metals may be present in a reduced
                                                                                                                                                     form oxidation of the metals though the
                                                                                                                                                     addition of compressed air or hydrogen
                                                                                                                                                     peroxide may be required prior to
                                                                                                                                                     precipitation.


                                                                                                                                                     JFH Typically recovered in oil water separators   Treatment systems may be fitted with systems
                                                                                                                                   Fats Oil and      which may be either be, open topped tanks,   which automatically remove the trapped
                                                                                                                                     Greases         inclined plate, coalescing media or utilise   oil and grease enabling the units to operate
                                                                                                                                                     dissolved air flotation.                  continuously.

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